click below
click below
Normal Size Small Size show me how
APES Chapter 15
Friedland
| Question | Answer |
|---|---|
| Air pollution | the addition of chemicals, particulate matter or microorganisms into the atmosphere at concentrations high enough to harm plants, animals, and materials or to alter ecosystems |
| Ground-level pollution | pollution of the troposphere |
| List the major air pollutants | sulfur dioxide, nitrogen oxides, carbon monoxide, particulate matter, tropospheric ozone and lead |
| Criteria air pollutants | the six major pollutants the EPA must specify allowable concentrations under the Clean Air Act |
| Sources of sulfur dioxide pollution | combustion of sulfur-containing fuels such as coal, oil, gasoline |
| Sources of nitrogen oxides pollution | combustion of fossil fuels, wood and other biomass |
| Sources of Carbon monoxide pollution | incomplete combustion, malfunctioning exhaust systems, poorly ventilated cooking fires |
| Sources of particulate matter pollution | combustion of fossil fuels and biofuels; agriculture, road construction |
| Sources of lead pollution | gasoline additive, oil and gasoline, coal, old paint |
| Sources of ozone pollution | a secondary pollutant formed from the reaction between sunlight, water, oxygen, VOCs and NOx |
| VOCs | volatile organic compounds; easily vaporized organic compounds such as gasoline, lighter fluid, dry-cleaning fluid, oil-based paints, perfumes |
| Source of VOC pollution | evaporation of fuels, solvents, paints; improper combustion of fuels such as gasoline |
| Sources of mercury pollution | coal, oil, gold mining |
| Sources of carbon dioxide pollution | combustion of fossil fuels and clearing of land |
| Effects/impacts of sulfur dioxide pollution | respiratory irritant (makes asthma worse_, hurts plant tissues, reacts with water to form sulfuric acid which leads to acid deposition |
| Equations for formation of sulfuric acid | SO2 + O2 --> SO3; SO3 + H2O --> H2SO4 |
| Effects/impacts of nitrogen oxides | respiratory irritant, ozone precursor, leads to photochemical smog, forms nitric acid which leads to acid deposition |
| Effects/impacts of carbon monoxide | bonds to hemoglobin in blood and interferes with oxygen transport; headaches at low concentrations; death at high concentrations |
| Effects/impacts of particulate matter | makes respiratory and heart disease worse; premature death; contributes to haze and smog |
| Effects/impacts of lead | harms central nervous system; reduces learning and ability to concentrate |
| Effects/impacts of ozone | reduces lung function; makes respiratory symptoms worse; degrades plant surfaces; damages rubber and plastics |
| Effects/impacts of VOC pollution | leads to ozone formation |
| Effects/impacts of mercury pollution | impairs central nervous system; bioaccumulates in the food chain |
| Effects/impacts of carbon dioxide pollution | a greenhouse gas that causes climate change |
| PM | particulate matter/particulates/particles; solid or liquid particles suspended in air |
| PM10 | particulate matter with a size between 2.5 – 10 micrometers |
| PM2.5 | particulate matter less than 2.5 micrometers in size; more dangerous than PM10 because they can get deeper into lungs and usually made of more toxic substances |
| Effect of PM pollution | large amounts reflect sunlight and can cool the planet |
| Primary air pollutants | air pollutants released directly into the atmosphere |
| Secondary air pollutants | air pollutants formed during chemical reactions in the atmosphere |
| Photochemical oxidants | secondary air pollutants formed when sunlight reacts with nitrogen oxides and sulfur dioxide; ex: ozone |
| Smog | a mixture of photochemical oxidants and particulate matter |
| Photochemical smog | smog dominated by photochemical oxidants; AKA brown smog |
| Sulfurous smog | smog dominated by sulfur dioxide and sulfate compounds; AKA gray smog |
| Atmospheric brown cloud | a combination of particulate matter and ozone; caused by combustion of fossil fuels and biomass |
| List primary pollutants | CO, CO2, SO2, NOx, PM, many VOCs |
| List secondary pollutants | SO3, H2SO4, O3, HNO3, H2O2, Most nitrates and sulfates ions |
| Natural air polluters | volcanoes,lightning, forest fires, plants (living and dead) |
| Percent of natural polluters | 30% SO2, 44% NOx, 89% VOCs are due to nature |
| What is the largest source of carbon monoxide and nitrogen oxides pollution? | transportation |
| What is the largest source of sulfur dioxide pollution? | coal-fired electric power plants |
| What is NAAQS? | National Ambient Air Quality Standards; the concentration limits for each air pollutant set by the EPA |
| What is the ozone standard? | not over 0.075 ppm in an 8-hour period for 4 days/year averaged over 3 years |
| Which pollutants still exceed NAAQS on a regular basis? | ozone and PM |
| Why have levels of lead pollutants decreased drastically? | lead is no longer added to gasoline |
| What is the “Black Triangle”? | one of the world’s most polluted areas in Germany, Poland and the Czech Republic where lignite is burned for electricity; |
| Formula for ozone | O3 |
| Equation for the forward reaction that creates ozone | NO2 + O2 + sunlight |
| Equation for the reverse reaction that removes ozone | O3 + NO |
| Is ozone a primary or secondary pollutant? | primary |
| What substances make up smog? | ozone and photochemical oxidants |
| Equation for the reaction that creates photochemical smog | the equation for ozone plus NO + VOCs |
| How does temperature affect the formation of smog? | increases emission of VOCs from plants; increases evaporation of VOCs; NOx increases from electricity demand; increase in reaction rate to form O3 |
| Thermal inversion | a warm air layer traps a cold air layer below; causes an increase in pollution concentrations |
| Why did over 1,000 people die in Tianjin, China due to a thermal inversion? | cold snap caused people to burn coal stoves which increased pollution that was trapped by thermal inversion |
| What is the pH of acid deposition? | lower than pH 5.6 |
| What pH causes developmental or reproductive problems in organisms? | less than pH 6.0 |
| What pH is often lethal for some organisms? | less than pH 5.0 |
| How is pH related to metal concentrations? | low pH causes metals to dissolve into water |
| How is acid deposition related to buildings? | acid deposition erodes limestone and marble buildings and statues |
| Fluidized bed combustion | removal of sulfur dioxide emissions during coal burning by passing the gasses through calcium carbonate |
| How can NOx’s be reduced? | cooler combustion temperatures; control the amount of oxygen during combustion; use of catalytic converters in cars; |
| How can Particulate Matter be reduced? | gravitational settling of ash in a smokestack; filtration; electrostatic precipitators; a scrubber |
| How can smog be reduced? | reduce VOC emissions; reduce nitrogen oxides emissions |
| Other ways to reduce pollution | reduce gasoline spills at gas stations, reduce evaporation of dry cleaning fluids; reduce number of wood-burning stoves; add HOV lanes to highways; limit number of cars on highways; add public transportation |
| What is the Acid Rain Program under the Clean Air Act? | allows the buying and selling of allowances to release a certain quantity of sulfur; overtime the number of allowances distributed has gradually been reduced thereby reducing sulfur emissions |
| What are the properties of UV-A radiation? | it passes through the atmosphere; it initiates skin cancer |
| What are the properties of UV-B and UV-C radiation? | they are higher energy than UV-A and can cause significant damage to the tissues and DNA of living organisms |
| How much UV radiation does the ozone layer absorb? | the ozone layer absorbs 99% of all incoming UV-B and UV-C radiation |
| Where is the ozone layer? | the stratosphere |
| What are the equations to form stratospheric ozone? | 2 O2 + UV-C --> 2 O3 |
| What is the equation when ozone absorbs UV radiation? | 2 O3 + UV-C or UV-B --> 3 O2 |
| Which anthropogenic chemicals destroy stratospheric ozone? | chlorofluorocarbons (CFCs); a class of chlorine-containing organic compounds often used in air conditioning, aerosol cans, etc. |
| How do CFCs destroy atmospheric ozone? | CFCs + UV --> releases Cl ; Cl acts as a catalyst in the reaction O3 + O --> 2 O2; one Cl can destroy 100,000 ozone molecules |
| What is the ozone hole? | Area over the Antarctic that experiences a seasonal depletion of stratospheric ozone |
| What are the effects of stratospheric ozone depletion? | a 4% increase of surface UV radiation between 1979 and 1992; increased numbers of skin cancer, cataracts and other eye problems |
| What is the Montreal Protocol? | ”The Montreal Protocol on Substances that Deplete the Ozone Layer”; countries agree to reduce CFC production and 95 other ozone-depleting compounds |
| Why will it take so long to see the amount of stratospheric chlorine decrease? | it should fall to about 1 ppb because CFCs are very stable, un-reactive and difficult to remove from the atmosphere |
| Why is indoor air pollution increasing? | 1. More time is being spent indoors. 2. Buildings are more insulated and tightly sealed. 3. More plastics in buildings that give off VOCs. |
| List some of the major indoor pollutants? | VOCs, Asbestos, carbon monoxide, radon |
| What is asbestos? | a silicate mineral used for insulation that causes lung cancer when the fine fibers get lodged in the lungs |
| What is radon? | a radioactive gas that occurs naturally in some rocks; seeps into homes through foundation cracks; 2nd leading cause of lung cancer |
| What is formaldehyde? | a VOC that is toxic and a carcinogen and is used to make building products such a cabinets and carpeting |
| What is sick building syndrome? | a problem with newer, air-tight buildings that allow a buildup of toxic compounds and pollutants; causes headaches, nausea, throat and eye irritations, fatigue |
| List the four reasons for sick building syndrome | inadequate or faulty ventilation; chemical contamination from indoor sources; chemical contamination from outdoor sources; biological contamination from molds and pollen |