Help
Options
Didn't know it?
click below
click below
Knew it?
click below
click below
Don't Know
Remaining cards (0)
Know
retry
shuffle
restart
0:00
Embed Code - If you would like this activity on your web page, copy the script below and paste it into your web page.
Normal Size Small Size show me how
Normal Size Small Size show me how
Organic Chemistry
MCAT Study Cards
| Question | Answer |
|---|---|
| Substrate: NaH and aldehyde/ketone | enolate formation |
| Substrate: LDA and aldehyde/ketone | enolate formation, approaches least hindered carbon |
| Substrate: NaOH + H2O and aldehyde | aldol condensation |
| Substrate: NaOH + H2O, heat, and aldehyde | aldol condensation with elimination |
| Substrate: NaCO3 and aldol with double bond | retro-aldol |
| Substrate: H2O and aldehyde/ketone | hydration |
| Substrate: TsOH, heat, ketone, and OH----OH | protecting group |
| Substrate: aldehyde, 1.Ag, OH, NH3, 2. H3O+ | oxdizing aldehyde (add OH group) |
| Substrate: NaBH4, EtOH, and primary or secondary aldehyde | alcohol formation |
| Substrate: 1. LAH, ether, 2. H3O+, carboxylic acid | alcohol formation |
| Substrate: carboxylic acid, primary amine, DCC | amide formation |
| Substrate: aldehyde, primary amine, HCl | imine formation |
| Substrate: aldehyde, secondary amine, HCl | enamine formation |
| Substrate: alcohol and Jones | carboxylic acid formation |
| Substrate: alcohol and PCC | aldehyde |
| Substrate: carboxylic acid, 1. NaOH, 2. Acyl chloride | acid anhydride formation |
| Substrate: carboxylic acid, 1. Br2, PBr3, 2. H2O | alpha substitution of carboxylic acid with bromine |
| Substrate: ketone, alcohol, H2SO4 | ester formation |
| Substrate: carboxylic acid, R'OH, HCl | esterification |
| 1H NMR 6.5-8 | aromatic |
| 1H NMR 5-6 | alkene |
| 1H NMR 9-10 | aldehyde |
| 1H NMR 0-1.8 | alkyl |
| 1H NMR 2 | alkyne |
| 1H NMR 2.5-4.5 | halogen, OR, amine |
| IR 1735-1680 | C=O |
| IR 1680-1620 | C=C |
| IR 2260-2100 | C triple bond |
| IR 2260-2220 | CN |
| IR 3300-2700 | C-C |
| IR 3150-2500, md | N-H |
| IR 3650-3200, br | O-H |
| Substrate: ketone, 1. MgBr-CR, ether, 2. H3O+ | carbon additions |
| Tollen's reagent Ag, and Benedict's reagent Cu | reduce sugars with hemiacetal groups |
| Ksp | solubility principle Ksp = concentrations of products # > Ksp results in precipitation |
| principal quantum number | size of an electron cloud |
| angular quantum number | shape of an orbital |
| magnetic quantum number | orientation in space of a particular orbital |
| degree of unsaturation | (2C + 2 + N-X-H)/2 |
| HCl | strong acid |
| HBr | strong acid |
| HI | strong acid |
| HNO3 | strong acid |
| HClO3 | strong acid |
| HClO4 | strong acid |
| H2SO4 | strong acid |
| LiOH | strong base |
| NaOH | strong base |
| KOH | strong base |
| RbOH | strong base |
| CsOH | strong base |
| Ca(OH)2 | strong base |
| Sr(OH)2 | strong base |
| Ba(OH)2 | strong base |
Created by:
missmartian
Popular MCAT sets