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Level 3 NCEA flsahcards

Quiz yourself by thinking what should be in each of the black spaces below before clicking on it to display the answer.
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Question
Answer
EN is.....   The measure of attraction an atom has for a pair of bonding electrons  
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IE is...   the minimium energy needed to remove an electron from an atom or ion in the gaseous state  
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AR is...   half the distance between the bonded nuclei  
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EN going across the periodic table...   Increases.  
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EN across the periodic table why...   becasue of the increasing number of protons so there is an increasing attration for electrons  
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IE going across the periodic table...   Increases  
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IE across the periodic table why...   becaue of the increasing attraction for electrons which means more energy is requied to remove them  
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AR going across the periodic table...   Decreases  
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AR across the periodic table why...   increasing attraction for electrons pulls the valance shell closer to the nucleus  
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EN going down the periodic table...   decreases  
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AR going down the periodic table why...   decreasing attraction for electrons so valance shell is further away from nucleus  
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EN going down the periodic table why...   increasing sheilding so there is a decrease in the attraction for electrons  
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IE going down the periodic table...   decreases  
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IE going down the periodic table why...   decreasing attraction for electrons so need less energy to remove them  
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AR going down the periodic table...   increases  
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Cations are what electrons   lost  
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anions are what electrons   gained  
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IR of positive ion   Fewer electrons are attracted more strongly to nucleus so IR is smaller than atom  
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IR of negitive ion   More electrons create more repultion betweeen elctrons so IR is bigger than atom  
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Pure covalent bond EN   0-0.5  
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Polar covalent bond EN   0.6-1.5  
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Ionic bond EN   1.6+  
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Forming anions   electrons are added into orbitals of increasing energy  
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Forming Cations   electrons are removed from 4s before 3d  
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[Ar]   1s2,2s2,2p6,3s2,3p6  
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Transition metals-Form complex ions   Central metal ion surrounded by ligands. Vacant 3d orbitals on t-metal ions accept these loan bonds  
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Transition metals-Form coloured compounds   Electrons in the incomplete 3d orbital absorb specific wave lengths of light energy. The colour seen is the light energy not absorbed  
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Transition metals-Make good catalysts   Vacant orbitals accept electron pairs from molecules. This strains the bonds in the molecules, encouraging reactions to occur  
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Lower oxidation states are   monatomic ions  
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Higher oxidation states   polyatomic ions  
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  T metals lose 4s electrons and then a varying number of unpaired 3d electrons to give varying oxidation states  
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2 Linear   2,180, symmetrical  
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Trigonal planar   3, 120, symmetrical  
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3 Angular bent   3, 120, asymmetrical  
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Tetrahedral   4, 109, symmetrical  
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Trigonal pyramidal   4, 107, asymmetrical  
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4 Angular bent   4,104.5, asymmetrical  
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Linear   4,109, asymmetrical  
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Trigonal bipyramidal   5, 90, 120, symmetrical  
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Seesaw   5, 90, 120, asymmetrical  
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T-shaped   5, 90, 120, asymmetrical  
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5 Linear   5, 90, 120, symmetrical  
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Octahedral   6, 90, symmetrical  
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Square-based pyramid   6, 90, asymmetrical  
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Square planar   6, 90, asymmetrical  
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Polar bond   unequally shared electrons between 2 atoms due to different EN  
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Polar molecule   has an uneven spread of charge  
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Non-polar bond   equally shared electrons between 2 identical atoms due to same EN  
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Non-polar molecule   even spread of charge  
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Intermolecular forces   forces within molecules or between ions  
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Examples of intermolecular forces   covalent bonds, ionic bonds  
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Covalent bonds   a strong attraction between atomic nuclei and shared pair of electrons.  
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Stronger covalent bonds   caused by more electrons being involved  
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Ionic bonding   strong EN attraction between cation and anion  
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Stronger ionic bonds   caused by higher charges  
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