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Chemistry unit 2
21 Polymerisation
Question | Answer |
---|---|
in organic chemistry small molecules can | join repeatedly to one another building up into a very large molecule called polymers. these small molecules are rather reactive molecules called monomers |
the 2 main types of polymerization processes | -addition polymerization -condensation polymerization |
polymers can exist either | -naturally -synthetic |
natural polymers are those that exist | in nature and include addition polymers such as rubber and condensation polymers such as proteins and carbohydrates |
synthetic polymers are | quite common and include addition polymers such as polyethene, poly vinyl chloride and polytetrafluroethene |
there are also condensation polymers which are | synthetic in origin such as nylon 6.6 and Terylene |
diagram type of polymers | dd |
addition polymers involves | the linking together of monomers with double or triple bonds. these unsaturated monomers have bonds which are able to break and link up with other monomers to form a repeating chain |
addition polymerization is involved in the manufacture of | polymers such as -polyethene, -poly vinyl chloride (PVC) and -polytetrafluroethene (PTFE) |
In the polymerization of ethene, many molecules of | the monomers add together to form a polymer |
the pi bond is broken to form | a free radical |
free radicals are | highly reactive chemical molecules with unpaired electrons. species such as H• and •OH. |
the free radicals mechanisms can be divided into | 3 stages -the initiation -the propagation -the termination |